Dilan M.Ratnayake et al. (2021) Novel nickel isolation procedure for a wide range of sample matrices without using dimethylglyoxime for isotope measurements using MC-ICP-MS, Analytica Chimica Acta, 1181, 338934, doi:10.1016/j.aca.2021.338934. < 20210819002742-680136 > pub

Map on Earth or stone. Places and analyses are shown.

  • abstract:

    Nickel isotope ratios have traditionally been used as an important tracer in cosmochemistry, and recently, it has gained attention in geochemistry, biochemistry, and environmental sciences with the development of MC-ICP-MS. Purification of Ni before isotope measurement is mandatory for obtaining precise data, which has been commonly achieved with ion-exchange chromatography, employing dimethylglyoxime (DMG) as a chelating agent for Ni. However, it has been pointed out that the use of DMG can adversely affect the isotope measurement due to insufficient Ni recovery and mass bias during measurement caused by the remaining DMG. Ni isolation procedures without the usage of DMG were innovated, but they have disadvantages such as the necessity of complex separation methods, high Ni blank, and matrix-dependent Ni recovery. Here, we present a simple Ni isolation procedure without using DMG but with the aid of oxalic acid along with common inorganic acids, achieving near-complete recovery of Ni with low blanks [0.7 ± 0.3 ng (2SD, n = 4)] only using three ion exchange column steps. To validate our method and strengthen the Ni isotope database of reference materials, 60Ni/58Ni of 20 geological reference materials, covering wide matrix compositions, were measured by MC-ICP-MS using the double-spike method. The results have shown that high recovery of Ni, independent of the sample matrix elements was achieved (98 ± 4%) and the 60Ni/58Ni was measured with a 2SD of 0.006–0.084‰ from samples containing 100–200 ng Ni.

  • doi: 10.1016/j.aca.2021.338934
  • modified at 2021-08-20
1: JP-1 2: PCC-1 3: DTS-1 4: TDB-1 5: UB-N 6: MUH-1 7: OKUM 8: BCR-2 9: JB-1b 10: AGV-2 11: JA-2 12: GSP-1 13: ref JSd-1


Img 1856 thumb GSP-1 < 20100824093541058.hkitagawa >pub
  • physical-form: powder
  • status: (unknown)
  • description: Split 74: Position 15
  • modified at 2021-08-20
Img 1859 thumb PCC-1 < 20100824093541348.hkitagawa >pub
  • classification: volcanic
  • physical-form: powder
  • status: (unknown)
  • description: US Geological Survey silicate reference material; peridotite; Split 22: Position 23
  • modified at 2021-08-20
Img 8254@f5b90dee968da254789bff3 thumb BCR-2 < 20130416090303-875743 >pub
  • classification: volcanic:basaltic
  • physical-form: powder
  • status: (unknown)
  • modified at 2021-08-20
Img 8255@fd978453fd4b62e245187e0 thumb AGV-2 < 20130416090310-185693 >pub
  • classification: volcanic:andesitic
  • physical-form: powder
  • status: (unknown)
  • modified at 2021-08-20
Tixhr 2054272387 thumb ref JSd-1 < 20180405163001-995930 >pub
  • classification: sedimentary
  • physical-form: powder
  • quantity (g): 60.17
  • description: Issued by the Geological Survey of Japan (GSJ)
  • modified at 2021-08-20
Img 5272 thumb DTS-1 < 20140606085058-007340 >pub
  • physical-form: powder
  • status: (unknown)
  • modified at 2021-08-20
Tixhr887022129 thumb JA-2 < 20160921101920-406882 >pub
  • classification: volcanic:andesitic
  • physical-form: powder
  • status: (unknown)
  • description: Geological Survey of Japan silicate reference material; andesite; split 9, position 56
  • modified at 2021-08-20
Tixhr 1512897544 thumb JB-1b < 20160921102320-366434 >pub
  • classification: volcanic:basaltic
  • physical-form: powder
  • status: (unknown)
  • description: Geological Survey of Japan silicate reference material - basalt; split 2, position 244
  • modified at 2021-08-20
Tixhr 164724045 thumb UB-N < 20190301105447-420882 >pub
  • physical-form: powder
  • quantity (g): 7.6
  • description: Serpentine-2015 lot (#296); SARM Reference Material
  • modified at 2021-08-20
Tixhr1155336349 thumb MUH-1 < 20190301105949-155966 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 100.0
  • description: Kraubath Harzburgite; IAG Certified Reference Material; split no: 329 of 1012
  • modified at 2021-08-20
Tixhr1798714881 thumb OKUM < 20190301110439-114181 >pub
  • classification: volcanic:basaltic
  • physical-form: powder
  • quantity (g): 100.0
  • description: Komatiitic Basalt, Ontario; IAG Certified Reference Material; split no. 58
  • modified at 2021-08-20
Tixhr 469706160 thumb TDB-1 < 20190301110815-447692 >pub
  • physical-form: powder
  • quantity (g): 394.6
  • description: Diabase; PGE Material; reference: Certificate of Analysis or CANMET Report CCRMP 94-1E
  • modified at 2021-08-20
Tixhr 854746915 thumb JP-1 < 20190301111946-454924 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 12.8
  • description: Harzburgite, GSJ; split 10, position 84
  • modified at 2021-08-20
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binder of Novel nickel isolation procedure for a wide range of sample matrices without using dimethylglyoxime for isotope measurements using MC-ICP-MS pub container 20210819015213-718098
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PCC-1_Cr-Ni-Cu-Zn pub HR-ICPMS Finningan, Element 4 20191009100319-761068
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PCC-1_Pb pub TIMS Thermo-Fisher MAT261 3 20191009104304-232542
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JA-2_S pub HR-ICPMS Finningan, Element 1 20191008141043-668614
JA-2_Cr-Ni-Cu-Zn pub HR-ICPMS Finningan, Element 4 20191009100320-146206
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JA-2_S (Max, 2012) pub ICPMS Thermo-Fisher Neptune 1 20191223153355-398443
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JB-1b_d56Fe pub ICPMS Thermo-Fisher Neptune 1 20191003113551-779082
JB-1b_Ni-Co-Fe-Mn-Cr pub ICPMS Thermo-Fisher Neptune 5 20191003145531-354097
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JP-1_d66Zn pub ICPMS Thermo-Fisher Neptune 1 20191003102339-458610
JP-1_d56Fe pub ICPMS Thermo-Fisher Neptune 1 20191003113551-906961
JP-1_Ni-Co-Fe-Mn-Cr pub ICPMS Thermo-Fisher Neptune 5 20191003145531-083716
JP-1_Ge-As-Se-Te pub Q-ICPMS Agilent 7500cs 4 20191004111800-014469
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JP-1_S (Max, 2012) pub ICPMS Thermo-Fisher Neptune 1 20191223153718-288546
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ref JSd-1-average pub TIMS Thermo-Fisher MAT262 1 20200129101958-660071
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name spots global-id
caption ID rowname stone
Ni mass fraction and δ60Ni value of reference materials pub 20210819012648-169988 Ni-d60Ni 13
manual
  • name
  • Dilan M.Ratnayake
  • Tanaka, Ryoji
  • Nakamura, Eizo